Breathing methyl chloroformate can irritate the nose and throat. There was no mutagenic effect of test material in the presence or absence of s9. Breathing methyl chloroformate can irritate the lungs. Keep unnecessary people away, isolate hazard area and deny. Section 5 fire fighting measures general information. Chlorocarbonic acid, methyl ester chloroformic acid, methyl ester methyl chlorocarbonate evacuate. Article methyl and ethyl chloroformate derivatizations for. Safety data sheet methyl chloroformate revision date.
The substance identifiers displayed in the infocard are the best available substance name, ec number, cas number andor the molecular and structural formulas. Disclaimer the sds samples above are collected from the internet by chemblink and displayed here for the tutorial purpose only. Articles of methyl chloroformate are included as well. Manufacturer importer supplier distributor information manufacturer vandemark chemical inc. Page 3 of 7 containers with water from unmanned hose holder or monitor nozzles until well after fire is out. It is a colorless liquid with a pungent odor, it is corrosive to metals and tissue. Reaction of 2aminothiazoles 1ab with various alkyl chloroformates 2ad, namely methyl chloroformate, ethyl chloroformate, propyl chloroformate and isobutyl chloroformate under dry conditions and in presence of pyridine 33 or triethylamine as the basic catalyst, afforded the corresponding carbamates 3ae. Methyl chloroformate is used in organic synthesis for the introduction of the methoxycarbonyl functionality to a suitable nucleophile i. The test material was completely soluble in ethanol. This material does not contain any hazardous air pollutants. Methyl chloroformate ch3ococl or c2h3clo2 cid 6586 structure, chemical names.
This fact sheet is a summary source of information of all. Methyl chloroformate mcf is generally used for the derivatization of functional groups such as carboxylic acids, amines, and phenols. Material safety data sheet methyl acetate section 1 chemical product and company identification msds name. To activate 3acylpyridines for nucleophilic addition with alkynyltin reagents to form 2,3disubstituted 1,2dihydropyridines. Methyl chloroformate 79221 tokyo chemical industry co. Methyl chloroformate is on the hazardous substance. Sds of ethyl chloroformate, safety data sheets, cas 5414. As in any fire, wear a selfcontained breathing apparatus in pressuredemand, mshaniosh approved. The substance identity section is calculated from substance identification information from all echa databases. As in any fire, wear a selfcontained breathing apparatus in pressuredemand, mshaniosh approved or equivalent, and full protective.
Palmitic acid methyl ester safety data sheet supersedes revision. Identification of the substancemixture and of the companyundertaking product name. Methyl chloroformate appears as a colorless liquid with a pungent odor. Methyl parathion 4 ec page 1 of 7 msds revision date ddmmyyyy. Address 1 north transit road, lockport, ny 14094 usa. Methods in molecular biology methods and protocols, vol 1198. Aldrich m35304 page 1 of 8 sigmaaldrich safety data sheet version 5. Safety data sheet chloromethyl chloroformate date prepared. Effects reported in humans due to acute shortterm inhalation exposure to methyl chloroform include hypotension, mild hepatic effects, and central nervous system cns depression. Search results for methyl chloroformate at sigmaaldrich. Methyl chloroformate article about methyl chloroformate by. Structure, properties, spectra, suppliers and links for. See actual entry in rtecs for complete information.
Our msds database is an easy to use, do it yourself tool, and best of all. Other companies are charging thousands of dollars to set up accounts and give you access to their msds online database. Eye contact rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Methyl chloroformate cas number 79221 eu number 2011873 index number. Methyl chloroformate mhc cautionary response information common synonyms liquid colorless to light yellow unpleasant odor sinks and reacts in water. Methyl formate revision date 25apr2019 general advice if symptoms persist, call a physician. Decomposes slowly in water to yield methanol, hcl, and co2. Show this safety data sheet to the doctor in attendance. Your new online msds binder is a place for you to store the material safety data sheets you need to deploy. Methyl chloroformate carbonochloridic acid, methylester 79221 5,000. Methyl chloroformate can affect you when breathed in. First aid measures as this product is a gas, refer to the inhalation section.
This material does not contain any class 1 ozone depletors. Calarp program combined 1 list of chemicals and threshold quantities tq chemical name. Quantitative analysis of amino and organic acids by methyl. Methyl chloroformate, with cas number of 79221, can be called carbonochloridic acid, methyl ester. Methyl chloroformate, 79221, acid halides, c2h3clo2 by loba chemie, india. Methyl chloroformate is incompatible with water, strong oxidizing agents, alcohols, bases including amines. Calarp program combined 1 list of chemicals and threshold.
Sds of methyl chloroformate, safety data sheets, cas 79221. Methyl chloroformate is incompatible with water, strong oxidizing agents, alcohols, bases. Methyl chloroformate is a highly corrosive chemical and contact can severely irritate and burn the skin and eyes with possible eye damage. Identification product identifier benzyl chloroformate other means of identification not available. The methyl chloroformate manufacturing companies are offering top quality products at suitable price. Methyl chloroformate manufacturers, suppliers and exporters. Osha no component of this product present at levels greater. Methyl 4hydroxybenzoate phydroxybenzoic acid methyl ester formula. To avoid the risk of static discharges and gas ignition, soak contaminated clothing thoroughly with water before removing it. The waste framework directive aims to protect the environment and human health from the generation and management of waste and to. Cas number, unna number, dot hazard label, uscg chris code. First aid measures general advice consult a physician. Methyl and ethyl chloroformate derivatizations for compoundspeci. In the absence of s9, the average numbers of mutants in controls in strains ta98, ta100, ta1535 all experiments, and ta1537 were 23, 149, 1618, and 10, respectively.
Chemical resistant protective gloves, butyl rubber, consult with glove manufacturer for testing data. Prevent further leakage or spillage if safe to do so. Get here the database of methyl chloroformate cas no 79221, methyl chloroformate manufacturers, suppliers and exporters. Methyl chloroformate is the methyl ester of chloroformic acid and is an oily liquid with a color that is anywhere from yellow to colorless. Methyl chloroformate hazard summary methyl chloroformate.439 1272 825 810 777 474 325 671 56 1495 1055 253 1387 1382 63 707 880 27 1019 394 21 326 1404 1167 1148 668 608 1422 754 351 456 488 1330 567 711 972 749 1329 630 1318 1023 708